Oxidative Dehydrogenation of Ethane on Oxide-Supported Vanadium Phosphorus Oxide Catalysts

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Resumo

Comparative results of studying the oxidative dehydrogenation of ethane (ODE) on catalytic vanadium-phosphorus oxide systems deposited by the molecular layering method on the surface of oxide supports (Al2O3, SiO2) have been presented. It has been found that the highest activity in ODE and selectivity for ethylene are exhibited by vanadium-phosphorus-containing catalysts. The influence of the acidity of catalytic systems on the activity and selectivity of the process has been revealed. The selectivity of the ODE process for ethylene reaches 90%. An increase in the oxygen concentration in the initial mixture from 3.5 to 20% leads mainly to a decrease in the selectivity of the ODE process with respect to the ethylene yield.

Sobre autores

A. Malygin

Saint Petersburg State Institute of Technology

Email: zhilyaeva@ips.ac.ru
190013, St. Petersburg, Russia

A. Yaroslavtsev

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: zhilyaeva@ips.ac.ru
119991, Moscow, Russia; 119991, Moscow, Russia

N. Zhilyaeva

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: zhilyaeva@ips.ac.ru
119991, Moscow, Russia

V. Elizarova

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: zhilyaeva@ips.ac.ru
119991, Moscow, Russia

E. Mironova

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: zhilyaeva@ips.ac.ru
119991, Moscow, Russia

A. Malkov

Saint Petersburg State Institute of Technology

Email: zhilyaeva@ips.ac.ru
190013, St. Petersburg, Russia

I. Bodalyov

Saint Petersburg State Institute of Technology

Autor responsável pela correspondência
Email: zhilyaeva@ips.ac.ru
190013, St. Petersburg, Russia

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Declaração de direitos autorais © Н.А. Жиляева, В.И. Елизарова, Е.Ю. Миронова, А.А. Малков, И.С. Бодалёв, А.А. Малыгин, А.Б. Ярославцев, 2023