Microwave-Assisted Hydrothermal Synthesis of Ceric-Ammonium Phosphates (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

The possibility of preparation of crystalline double cerium(IV) phosphates (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3 under the conditions of microwave-assisted hydrothermal synthesis has been analyzed. It has been shown that these phosphates in a single-phase state can be obtained in the temperature range of 130–190°С with a synthesis duration of ≥5 min, while the phase composition of the synthesis products is determined by the molar ratio of ammonia and phosphoric acid in the reaction mixture. Short-term (5 min) low-temperature (130°С) hydrothermal synthesis under microwave heating leads to the preparation of (NH4)2Ce(PO4)2⋅H2O and NH4Ce2(PO4)3 with a particle size of ~70 and ~200 nm, respectively. At higher temperatures and treatment times (190°C and 24 h), the particle size of these phases increases to ~200 and ~500 nm, respectively. For the first time, the value of the optical band gap for (NH4)2Ce(PO4)2⋅H2O was determined to be 2.8 and 3.1 eV for indirect and direct transitions, respectively.

Негізгі сөздер

Авторлар туралы

I. Tronev

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

E. Sheichenko

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

L. Razvorotneva

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

E. Trufanova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

P. Minakova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

T. Kozlova

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: van@igic.ras.ru
119991, Moscow, Russia

A. Baranchikov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: van@igic.ras.ru
119991, Moscow, Russia

V. Ivanov

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; National Research University Higher School of Economics

Хат алмасуға жауапты Автор.
Email: van@igic.ras.ru
119991, Moscow, Russia; 101000, Moscow, Russia

Әдебиет тізімі

  1. Nazaraly M., Wallez G., Chanéac C. et al. // Angew. Chem. Int. Ed. 2005. V. 44. P. 5691. https://doi.org/10.1002/anie.200501871
  2. Nazaraly M., Wallez G., Chanéac C. et al. // J. Phys. Chem. Solids. 2006. V. 67. P. 1075. https://doi.org/10.1016/j.jpcs.2006.01.028
  3. Козлова Т.О., Баранчиков А.Е., Иванов В.К. // Журн. неорган. химии. 2021. Т. 66. № 12. С. 1647. https://doi.org/10.31857/s0044457x21120102
  4. Bevara S., Achary S.N., Patwe S.J. et al. // AIP Conf. Proc. 2016. V. 1731. P. 1. https://doi.org/10.1063/1.4948206
  5. Nazaraly M., Quarton M., Wallez G. et al. // Solid State Sci. 2007. V. 9. P. 672. https://doi.org/10.1016/j.solidstatesciences.2007.04.021
  6. Achary S.N., Bevara S., Tyagi A.K. // Coord. Chem. Rev. 2017. V. 340. № March. P. 266. https://doi.org/10.1016/j.ccr.2017.03.006
  7. Romanchuk A.Y., Shekunova T.O., Larina A.I. et al. // Radiochemistry. 2019. V. 61. № 6. P. 719. https://doi.org/10.1134/S1066362219060134
  8. Sato T., Li R., Sato C. et al. // Phosphorus Res. Bull. 2007. V. 21. P. 44. https://doi.org/10.3363/prb.21.44
  9. Sato T., Yin S. // Phosphorus Res. Bull. 2010. V. 24. P. 43. https://doi.org/10.3363/prb.24.43
  10. Sato T., Sato C., Yin S. // Phosphorus Res. Bull. 2008. V. 22. P. 17. https://doi.org/10.3363/prb.22.17
  11. Kozlova T.O., Popov A.L., Kolesnik I.V. et al. // J. Mater. Chem. B. 2022. V. 10. № 11. P. 1775. https://doi.org/10.1039/d1tb02604f
  12. Nazaraly M., Chanéac C., Ribot F. et al. // J. Phys. Chem. Solids. 2007. V. 68. P. 795. https://doi.org/10.1016/j.jpcs.2007.03.010
  13. Shekunova T.O., Istomin S.Y., Mironov A.V. et al. // Eur. J. Inorg. Chem. 2019. V. 2019. № 27. P. 3242. https://doi.org/10.1002/ejic.201801182
  14. Kozlova T.O., Mironov A.V., Istomin S.Y. et al. // Chem. A Eur. J. 2020. V. 26. № 53. P. 12188. https://doi.org/10.1002/chem.202002527
  15. Lai Y., Chang Y., Wong T. et al. // Inorg. Chem. 2013. V. 52. № 23. P. 13639.
  16. Salvado M.A., Pertierra P., Trobajo C. et al. // J. Am. Chem. Soc. 2007. V. 129. № 36. P. 10970.
  17. Shekunova T.O., Baranchikov A.E., Ivanova O.S. et al. // J. Non-Cryst. Solids. 2016. V. 447. P. 183. https://doi.org/10.1016/j.jnoncrysol.2016.06.012
  18. Zhu Y.J., Chen F. // Chem. Rev. 2014. V. 114. № 12. P. 6462. https://doi.org/10.1021/cr400366s
  19. Meng L.Y., Wang B., Ma M.G. et al. // Mater. Today Chem. 2016. V. 1–2. P. 63. https://doi.org/10.1016/j.mtchem.2016.11.003
  20. Moreira M.L., Mambrini G.P., Volanti D.P. et al. // Chem. Mater. 2008. V. 20. № 16. P. 5381. https://doi.org/10.1021/cm801638d
  21. Salvadó M.A., Pertierra P., Bortun A.I. et al. // Inorg. Chem. 2008. V. 47. № 16. P. 7207. https://doi.org/10.1021/ic800818c
  22. Petit S., Righi D., Madejová J. // Appl. Clay Sci. 2006. V. 34. № 1–4. P. 22. https://doi.org/10.1016/j.clay.2006.02.007
  23. Petit S., Righi D., Madejová J. et al. // Clay Miner. 1999. V. 34. P. 543.
  24. Kloprogge J.T., Broekmans M., Duong L.V. et al. // J. Mater. Sci. 2006. V. 41. № 11. P. 3535. https://doi.org/10.1007/s10853-005-5909-5
  25. Xu Y., Feng S., Pang W. et al. // Chem. Commun. 1996. № 11. P. 1305. https://doi.org/10.1039/CC9960001305
  26. Brandel V., Clavier N., Dacheux N. // J. Solid State Chem. 2005. V. 178. № 4. P. 1054. https://doi.org/10.1016/j.jssc.2005.01.005
  27. Skogareva L.S., Shekunova T.O., Baranchikov A.E. et al. // Russ. J. Inorg. Chem. 2016. V. 61. № 10. P. 1219. https://doi.org/10.1134/S0036023616100181
  28. Hadrich A., Lautie A., Mhiri T. et al. // Vib. Spectrosc. 2001. V. 26. P. 51.
  29. Yang G., Park S.-J. // Materials (Basel). 2019. V. 12. № 7. P. 1177. https://doi.org/10.3390/ma12071177
  30. Maksimov V.D., Meskin P.E., Churagulov B.R. // Inorg. Mater. 2007. V. 43. № 9. P. 988. https://doi.org/10.1134/S0020168507090142
  31. Zhou H., Zhang M., Kong S. et al. // Mater. Lett. 2016. V. 180. P. 239. https://doi.org/10.1016/j.matlet.2016.05.165
  32. Qi C., Zhu Y.-J., Sun T.-W. et al. // Chem. An Asian J. 2015. V. 10. № 11. P. 2503. https://doi.org/10.1002/asia.201500667
  33. Sakintuna B., Yürüm Y. // J. Porous Mater. 2010. V. 17. № 6. P. 727. https://doi.org/10.1007/s10934-009-9344-x
  34. Yu Y.-H., Chen Y.-P., Zeng M. et al. // Mater. Lett. 2016. V. 163. P. 158. https://doi.org/10.1016/j.matlet.2015.10.039
  35. Kolesnik I.V., Aslandukov A.N., Arkhipin A.S. et al. // Crystals. 2019. V. 9. № 7. P. 332. https://doi.org/10.3390/cryst9070332

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© И.В. Тронев, Е.Д. Шейченко, Л.С. Разворотнева, Э.А. Труфанова, П.В. Минакова, Т.О. Козлова, А.Е. Баранчиков, В.К. Иванов, 2023