Extraction of REE(III) with Mixtures of 2,4,6-tris(Diarylphosphoryl)-1,3,5-triazines and Picrolonic Acid

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

Considerable synergetic effect has been revealed on extraction of REE(III) ions from chloride solutions with mixtures of picrolonic acid and tris(diarylphosphoryl)-1,3,5-triazines in 1,2-dichloroethane due to formation of hydrophobic mixed-ligand REE(III) complexes. Parameters of extraction equilibrium and stoichiometry of resulting complexes have been determined. Effect of aqueous phase composition, organic solvent nature, and extractant structure has been studied. The largest synergetic effect has been observed in the system with tris(ditolylphosphoryl)-1,3,5-triazine.

Авторлар туралы

A. Turanov

Yu.A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences

Email: turanov@issp.ac.ru
142432, Chernogolovka, Moscow oblast, Russia

V. Karandashev

Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences

Email: matveeva@gmail.com
142432, Chernogolovka, Moscow oblast, Russia

O. Artyushin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: matweeva@gmail.com
119991, Moscow, Russia

E. Smirnova

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: matveeva@gmail.com
119991, Moscow, Russia

G. Bodrin

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Email: matveeva@gmail.com
119991, Moscow, Russia

V. Brel

Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: v_brel@mail.ru
119991, Moscow, Russia

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© А.Н. Туранов, В.К. Карандашев, О.И. Артюшин, Е.В. Смирнова, Г.В. Бодрин, В.К. Брель, 2023